The azo compounds synthesized from substituted 2-aminobenzothiazoles were scientifically significant for synthetic organic colorants compounds, sensor, nano chemistry and pharmaceutically and industrially very important for technically useful applications. Azo group compounds are commonly used in preparation of or as synthetic colour molecules. They are prepared beginning with primary aromatic amines by diazotization and coupling on aromatic mofits. The compounds were studied to arrive at their skeleton using different type of data (spectroscopic and the analytical) using spectroscopies such as UV-Vis., FT-IR, 1H-NMR. Azo compounds of amino benzothiazole have varied applications in pigments, many used in food, cosmetics and drug industry as well.