1.Why Record Spectra of Astronomical Objects? 1.1 A Historical Introduction 1.2 What One Can Learn from Studying Spectra
2.The Nature of Spectra 2.1 Transitions 2.2 Absorption and Emission 2.3 Other Measures of Transition Probabilities 2.4 Stimulated Emission 2.5 Optical Depth 2.6 Critical Density 2.7 Wavelength or Frequency? 2.8 The Electromagnetic Spectrum
3.Atomic Hydrogen 3.1 Overview 3.2 The Schrodinger Equation of Hydrogen-Like Atoms 3.3 Reduced Mass 3.4 Atomic Units 3.5 Wavefunctions for Hydrogen 3.6 Energy Levels and Quantum Numbers 3.7 H-Atom Discrete Spectra 3.8 H-Atom Spectra in Different Locations 3.8.1 Balmer series 3.8.2 Lyman series 3.8.3 Infrared lines 3.9 H-Atom Continuum Spectra 3.9.1 Processes 3.9.2 H-atom emission in H II regions 3.10 Radio Recombination Lines 3.11 Radio Recombination Lines for Other Atoms 3.12 Angular Momentum Coupling in the Hydrogen Atom 3.13 The Fine Structure of Hydrogen 3.14 Hyperfine Structure in the H Atom 3.15 Allowed Transitions 3.16 Hydrogen in Nebulae
4.Complex Atoms 4.1 General Considerations 4.2 Central Field Model 4.3 Indistinguishable Particles 4.4 Electron Configurations 4.5 The Periodic Table 4.6 Ions 4.7 Angular Momentum in Complex Atoms 4.7.1 L-S or Russell-Saunders coupling 4.7.2 j-j coupling 4.7.3 Why two coupling schemes? 4.8 Spectroscopic Notation 4.9 Parity of the Wavefunction 4.10 Terms and Levels in Complex Atoms
5.Helium Spectra 5.1 He I and He II Spectra 5.2 Selection Rules for Complex Atoms 5.3 Observing Forbidden Lines 5.4 Grotrian Diagrams 5.5 Potential Felt by Electrons in Complex Atoms 5.6 Emissions of Helium-Like Ions
6.Alkali Atoms 6.1 Sodium 6.2 Spin-Orbit Interactions 6.3 Fine Structure Transitions 6.4 Astronomical Sodium Spectra 6.5 Other Alkali Metal-Like Spectra
7.Spectra of Nebulae 7.1 Nebulium 7.2 The Bowen Mechanism 7.3 Two Valence Electrons 7.4 Autoionisation and Recombination
8.Spectra in Magnetic Fields 8.1 Uniform Magnetic Field 8.2 Strong Magnetic Field 8.3 Weak Magnetic Field 8.3.1 The normal Zeeman effect 8.3.2 The anomolous Zeeman effect 8.4 Spectra in Magnetic Field
9.X-Ray Spectra 9.1 Inner Shell Processes 9.2 The Solar Corona 9.3 The Structure of Highly Ionised Atoms 9.4 Isotope Effects
10.Molecular Structure 10.1 The Born-Oppenheimer Approximation 10.2 Electronic Structure of Diatomics 10.2.1 Labelling of electronic states 10.2.2 Symmetry 10.2.3 State labels 10.3 Schrodinger Equation 10.3.1 Nuclear motion in diatomic molecules 10.4 Fractionation 10.5 Vibration-Rotation Energy Levels 10.6 Temperature Effects 10.6.1 Rotational state populations 10.6.2 Vibrational state populations 10.6.3 Electronic state populations
11.Rotational Spectra 11.1 Rotational Structure of Polyatomic Molecules 11.2 Selection Rules: Pure Rotational Transitions 11.3 Selection Rules 11.4 Isotope Effects 11.5 Rotational Spectra of Other Molecules 11.6 Rotational Spectra of Molecular Hydrogen 11.7 Maser Emissions
12.Vibration-Rotation Spectra 12.1 Vibrations in Polyatomic Molecules 12.2 Vibrational Transitions 12.2.1 Structure of the spectrum 12.2.2 Isotope effects 12.2.3 Hydrogen molecule vibrational spectra 12.3 Astronomical Spectra